Surface functionalization of microporous carbon fibers by vapor phase methods for CO<sub>2</sub> capture
نویسندگان
چکیده
The removal of excess CO 2 from the atmosphere is expected to play a major role in mitigation global warming. Solid-state adsorbents, consisting -binding functionalities on porous supports, can provide high capture capacities with low energy requirements. In this contribution, we report vapor-phase functionalization carbon fibers amine functionalities. Functionalization occurs either via direct exposure cyclic azasilane molecules (2,2-dimethoxy-1,6-diaza-2-silacyclooctane) or by atomic layer deposition Al O 3 followed azasilane. XPS analysis and SEM/energy-dispersive x-ray spectroscopy (EDX) measurements confirmed functionalization. Yet, two different approaches led loadings distinct differences porosity upon functionalization, which affected capture. Combining resulted fast sorption superior capturing efficiency. contrast, strong reduction surface area support limited gas exchange. We attribute efficiency level achieved when combining demonstrating that approach might be valuable for compact high-throughput air, systems.
منابع مشابه
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ژورنال
عنوان ژورنال: Journal of vacuum science & technology
سال: 2023
ISSN: ['2327-9877', '0734-211X']
DOI: https://doi.org/10.1116/6.0002419